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PFAS in groundwater: state-by-state regulations

PFAS in groundwater: state-by-state regulations

Oct 24, 2023
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Summary

In the absence of federal cleanup standards for per- and polyfluoroalkyl substances (“PFAS”) in groundwater, several states have started the process of regulating PFAS in groundwater themselves.  As a result, states have adopted a patchwork of regulations and guidance standards that present significant compliance challenges to impacted industries.  This client alert explores the current landscape of state regulations regarding the advisory, notification, and cleanup levels for PFAS – typically perfluorooctane sulfonic acid (“PFOS”) and perfluorooctanoic acid (”PFOA”)  – in groundwater.

Federal Regulations

In 2019, the United States Environmental Protection Agency (“EPA”) issued interim recommendations to address groundwater contaminated with PFOA and PFOS, but that guidance was subsequently rescinded.  Although EPA concluded that the interim recommendation “no longer reflects the best, currently available science,” the fact sheet discussing the 2019 interim recommendations is still a helpful resource to understand how EPA was evaluating the issue at that time.

State Regulations

The snapshot provided below is current as of October 17, 2023 but it is important to note that this is a developing regulatory space.  Some states, such as Florida and Rhode Island, have proposed groundwater regulations, or have indicated that they will revise groundwater regulations, for various PFAS substances that may take effect soon. 

Businesses should consider whether they currently use or discharge any PFAS compounds which may reach groundwater and evaluate if any state regulations apply, particularly if they operate in any of the below-listed jurisdictions.  In addition, owners of property with legacy PFAS use, and prospective purchasers of commercial and industrial properties, should review the most current groundwater quality standards as part of the due diligence process.

Additionally, in November of 2022, a Michigan court suspended the use of that state’s MCLs for seven PFAS compounds, finding that the agency had not adequately explained its analysis of the cost impacts of the proposed law in the regulatory impact statement.  The court stayed the impact of the ruling until the court issues a final judgment, and on August 22, 2023, the Michigan Court of Appeals held that the Michigan agency establishing the MCLs did not adhere to the necessary administrative protocols.  At this time, it is unclear whether this decision will be overturned or affirmed on appeal.  These Michigan decisions highlight the tension between the regulatory intent and the resulting cost, and further litigation is expected as more states – and eventually the federal government - enact similar legislation.  Additionally, these decisions emphasize that PFAS groundwater regulations are currently being evaluated (and potentially modified) shortly.

 

States that have adopted a standard lower than 70 ppt

 

Concentration Level

2 ppt (stated by the Illinois Pollution Control Agency as 2 ng/L)

Type of Regulation

PFOA (Advisory)

Information

Regulation and related information


Concentration Level

14 ppt (stated by the Illinois Pollution Control Agency as 14 ng/L)

Type of Regulation

PFOS (Advisory)

Information

Regulation and related information


Concentration Level

21 ppt (stated by the Illinois Pollution Control Agency as 21 ng/L)

Type of Regulation

PFNA (Advisory)

Information

Regulation and related information

Concentration Level

0.004 ppt for protected groundwater sources (stated by the Iowa Department of Natural Resources as 0.000000004 mg/L)

Type of Regulation

PFOA (Advisory)

Information

Statewide Standards


Concentration Level

0.02 ppt for protected groundwater sources (stated by the Iowa Department of Natural Resources as 0.00000002 mg/L)

Type of Regulation

PFOS (Advisory)

Information

Statewide Standards


Concentration Level

21 ppt for protected groundwater sources (stated by the Iowa Department of Natural Resources as 0.000021 mg/L)

Type of Regulation

PFNA (Advisory)

Information

Statewide Standards

Concentration Level

20 ppt (stated in the regulation as .02 ppb)

Type of Regulation

6 PFAS Substances combined: PFOA, PFOS, PFHxS, PFNA, PFHpA, and PFDA (Clean Up)

Information

Regulation and related information

Concentration Level

6 ppt

Type of Regulation

PFNA (Clean Up)

Information

Regulation and related information


Concentration Level

8 ppt

Type of Regulation

PFOA (Clean Up)

Information

Regulation and related information


Concentration Level

16 ppt

Type of Regulation

PFOS (Clean Up)

Information

Regulation and related information


Concentration Level

51 ppt

Type of Regulation

PFHxS (Clean Up)

Information

Regulation and related information

Concentration Level

15 ppt (stated by the Minnesota Department of Health as 0.015 ppb)

Type of Regulation

PFOS (Advisory)

Information

Health Advisory Level and related information


Concentration Level

35 ppt

Type of Regulation

PFOA (Advisory)

Information

Health Advisory Level (see page 181) and related information


Concentration Level

47 ppt

Type of Regulation

PFHxS (Advisory)

Information

Health Advisory Level (see page 180) and Related Information

Concentration Level

11 ppt

Type of Regulation

PFNA (Clean Up)

Information

Regulation and related information


Concentration Level

12 ppt

Type of Regulation

PFOA (Clean Up)

Information

Regulation and related information


Concentration Level

15 ppt

Type of Regulation

PFOS (Clean Up)

Information

Regulation and related information


Concentration Level

18 ppt

Type of Regulation

PFHxS (Clean Up)

Information

Regulation and related information

Concentration Level

2 ppt (stated by the regulation as 0.002 µg/L)

Type of Regulation

Chloroperfluoropolyether carbonates[1] (Clean Up)

Information

Interim Specific Groundwater Quality Criterion and related information


Concentration Level

13 ppt

Type of Regulation

PFNA and PFOS (Clean Up)

Information

Regulation and related information


Concentration Level

14 ppt

Type of Regulation

PFOA (Clean Up)

Information

Regulation and related information


Concentration Level

20 ppt (stated in the regulation as .02 µg/L)

Type of Regulation

HFPO-DA or Gen X (Clean Up)

Information

Interim Specific Ground Water Quality Criterion and related information

Concentration Level

0.004 ppt (stated by the North Carolina Department of Environmental Quality as a value below the practical quantification limit, or PQL)

Type of Regulation

PFOA (Advisory)

Information

EPA’s Interim Health Advisory and related information

Concentration Level

20 ppt (stated in the regulation as .02 µg/L)

Type of Regulation

5 PFAS substances combined:  PFHpA, PFHxS, PFNA, PFOS and PFOA (Notification)

Information

Regulation and related information

Concentration Level

9 ppt (stated by the Washington Department of Ecology as 9 ng/L)

Type of Regulation

PFNA (Advisory)

Information

Related information


Concentration Level

10 ppt (stated by the Washington Department of Ecology as 10 ng/L)

Type of Regulation

PFOA (Advisory)

Information

Related information


Concentration Level

15 ppt (stated by the Washington Department of Ecology as 15 ng/L)

Type of Regulation

PFOS (Advisory)

Information

Related information


Concentration Level

24 ppt (stated by the Washington Department of Ecology as 24 ng/L)

Type of Regulation

HFPO-DA or GenX (Advisory)

Information

Related information


Concentration Level

65 ppt (stated by the Washington Department of Ecology as 65 ng/L)

Type of Regulation

PFHxS (Advisory)

Information

Related information

States that have adopted a standard equal to 70 ppt

 

Concentration Level

70 ppt

Type of Regulation

Site-specific Standard for PFOA and PFOS (Clean Up)

Information

Site-Specific Groundwater Quality Standard (pgs. 8-12)

Concentration Level

70 ppt

Type of Regulation

Follow the EPA Health Advisory Level: PFOS and PFOA combined (Advisory)

Information

PFAS Dynamic Plan (pg. 9)

Concentration Level

70 ppt

Type of Regulation

PFOS + PFOA + PFHpA + PFNA + PFHxS < 70 ppt (Advisory)

Note: Maine has both residential and construction standards

Information

Maximum Exposure Guideline (pgs. 36 and 60) and related information

Concentration Level

70 ppt

Type of Regulation

Follow the EPA Health Advisory Level: PFOS and PFOA combined (Potential Clean Up)

Information

Numeric Water Quality Standard (pg. 60) and related information

Concentration Level

70 ppt

Type of Regulation

Follow the EPA Health Advisory Level: PFOS and PFOA combined (Clean Up)

Information

Medium Specific Concentration Cleanup Standards and related information

Concentration Level

70 ppt

Type of Regulation

Follow the EPA Health Advisory Level: PFOS and PFOA combined (Notification)

Information

Department of Environment Management Groundwater Quality Standard

States that have adopted a standard higher than 70 ppt

 

Concentration Level

400 ppt (stated in the regulation as 0.4 µg/L)

Type of Regulation

PFOA and PFOS separately (Clean Up)

Information

Regulation (18 AAC 75) and related information

Concentration Level

140 ppt (stated by the Illinois Pollution Control Agency as 140 ng/L)

Type of Regulation

PFHxS (Advisory)

Information

Regulation and related information


Concentration Level

2,100 ppt (stated by the Illinois Pollution Control Agency as 2,100 ng/L)

Type of Regulation

PFBS (Advisory)

Information

Regulation and related information


Concentration Level

560,000 ppt (stated by the Illinois Pollution Control Agency as 560,000 ng/L)

Type of Regulation

PFHxA (Advisory)

Information

Regulation and related information

Concentration Level

400,000 ppt (stated in the regulation as 400 µg/L)

Type of Regulation

PFBS (Advisory)

Information

Screening Levels

Concentration Level

140 ppt for protected groundwater sources (stated by the Iowa Department of Natural Resources as 0.00014 mg/L)

Type of Regulation

PFHxS (Advisory)

Information

Statewide Standards


Concentration Level

2,000 ppt for protected groundwater sources (stated by the Iowa Department of Natural Resources as 0.002 mg/L)

Type of Regulation

PFBS (Advisory)

Information

Statewide Standards


Concentration Level

3,500 ppt for protected groundwater sources (stated by the Iowa Department of Natural Resources as 0.0035 mg/L)

Type of Regulation

PFHxA (Advisory)

Information

Statewide Standards


Concentration Level

7,000 ppt for protected groundwater sources (stated by the Iowa Department of Natural Resources as 0.007 mg/L)

Type of Regulation

PFBA (Advisory)

Information

Statewide Standards

Concentration Level

400,000 ppt (stated in the regulation as 400 ppb)

Type of Regulation

PFBS (Advisory)

Note: Maine has both residential and construction standards

Information

Maximum Exposure Guideline (see pg. 60)

Concentration Level

370 ppt

Type of Regulation

HFPO-DA (Clean Up)

Information

Regulation and related information


Concentration Level

420 ppt

Type of Regulation

PFBS (Clean Up)

Information

Regulation and related information


Concentration Level

400,000 ppt

Type of Regulation

PFHxA (Clean Up)

Information

Regulation and related information

Concentration Level

2,000 ppt

Type of Regulation

PFBS (Advisory)

Information

Health Advisory Level (see pg. 180) and related information


Concentration Level

7,000 ppt

Type of Regulation

PFBA (Advisory)

Information

Health Advisory Level (see pg. 180) and related information

Concentration Level

667 ppt (stated in the regulation as 0.667 µg/L)

Type of Regulation

PFOS and PFOA (Advisory)

Information

Basic Comparison Levels and related information


Concentration Level

667,000 ppt (stated in the regulation as 667 µg/L)

Type of Regulation

PFBS (Advisory)

Information

Basic Comparison Levels and related information

Concentration Level

10,000 ppt (stated in the regulation as 10 µg/L)

Type of Regulation

PFBS Residential Property (Clean Up)

Information

Medium-Specific Concentration Standards and related information


Concentration Level

29,000 ppt (stated in the regulation as 29 µg/L)

Type of Regulation

PFBS Non-residential Property (Clean Up)

Information

Medium-Specific Concentration Standards and related information

Concentration Level

345 ppt (stated by the Washington Department of Ecology as 345 ng/L)

Type of Regulation

PFBS (Advisory)

Information

Related information

Individual PFAS standards

 

Concentration Level

40 ppt, etc.

Type of Regulation

PFOA and PFOS; 17 other PFAS substances (Advisory) including the following: PFNA and PFDA (.004 µg/L); PFUnDA (.01 µg/L); PFDoDA and PFTrDA (.013 µg/L); PFHxS (.019 µg/L); PFHpS and PFDS (.02 µg/L); PFOSA (.024 µg/L);  PFTeDA (.13 µg/L); HFPO-DA (.16 µg/L); PFHpA (0.4 µg/L); PFBS (.6 µg/L); 6:2 FTS (.78 µg/L); PFPeA (.8 µg/L); PFHxA (4.0 µg/L ); and PFBA (7.6 µg/L).

Information

Environmental Action Levels (see pg. 48)

Concentration Level

290 ppt, etc.

Type of Regulation

16 Different PFAS Substances (Clean Up)

Texas has 15 additional regulations, including the following:  PFHxS, PFHxA, and PFPeA (93 ppt); PFNA, PFDS, PFUnA, PFOSA, PFTrDA, PFTeA, and PFDoA (290 ppt); PFDA (370 ppt); PFOS and PFHpA (560 ppt); PFBS (34,000 ppt); and PFBA (71,000 ppt).  A reader-friendly summary of these limitations can be found at a publication from the Reese Air Force Base.

Information

Protective Concentration Levels (see May 2023 Tier 1 PCL Tables)

Related information

 

*at date of publication

  • Alabama
  • Arizona
  • Arkansas
  • California
  • Connecticut
  • Delaware
  • Georgia
  • Idaho
  • Kansas
  • Kentucky
  • Louisiana
  • Maryland
  • Mississippi
  • Missouri
  • Nebraska
  • New Mexico
  • New York
  • North Dakota
  • Ohio
  • Oklahoma
  • Oregon
  • South Carolina
  • South Dakota
  • Tennessee
  • Utah
  • Virginia
  • West Virginia
  • Wisconsin
  • Wyoming

Notification

A corporate representative must inform the appropriate state official that the groundwater is above the stated limit.

Advisory

These levels are not binding limits, but they can serve as the basis for regulatory action, and are a useful tool for due diligence and risk assessment.

Clean Up

Investigation and remediation is usually required when concentration levels exceed the clean up threshold.  This is usually expressed by groundwater quality standards that identify specific clean up criteria.

Additional Information

Without federal PFAS standards for groundwater, states have enacted a wide range regulatory concentration levels.  For example, for PFAS substances in groundwater, one of the most stringent concentration limits is 0.004 ppt (Iowa; PFOA only) and the most lenient concentration is 667,000 ppt (Nevada; PFBS only).  The following chart demonstrates that even for PFOA and PFOS, which have been more extensively studied and regulated than other PFAS compounds, there is still a wide discrepancy in the values that different states have adopted.

Conclusion

Businesses operating in the 21 states where groundwater regulations have already been enacted should consider whether they currently use or discharge any of the regulated PFAS compounds.  In addition, owners of property with legacy PFAS use, and prospective purchasers of commercial and industrial properties in these jurisdictions will increasingly need to incorporate the groundwater quality standards as part of their due diligence processes.

For more information on PFAS chemicals, and the regulatory and litigation risks that they pose, please visit our PFAS webpage. If you have a question about how to manage PFAS risk in any jurisdiction, contact Tom Lee, John Kindschuh, Emma Cormier, or any other member of our PFAS team at Bryan Cave Leighton Paisner LLP.

Related Practice Areas

  • PFAS Team

  • Environment

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This material is not comprehensive, is for informational purposes only, and is not legal advice. Your use or receipt of this material does not create an attorney-client relationship between us. If you require legal advice, you should consult an attorney regarding your particular circumstances. The choice of a lawyer is an important decision and should not be based solely upon advertisements. This material may be “Attorney Advertising” under the ethics and professional rules of certain jurisdictions. For advertising purposes, St. Louis, Missouri, is designated BCLP’s principal office and Kathrine Dixon (kathrine.dixon@bclplaw.com) as the responsible attorney.